DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) CAS: 12148-71-9
Catalog Number | XD94450 |
Product Name | DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) |
CAS | 12148-71-9 |
Molecular Formula | C18H22Ir2O2 |
Molecular Weight | 654.81 |
Storage Details | Ambient |
Product Specification
Appearance | White powder |
Assay | 99% min |
Di-mu-methoxobis(1,5-cyclooctadiene)diiridium(I), also known as Ir2(cod)2O2, is an important organometallic compound widely used as a catalyst in various organic transformations.One of the primary applications of Ir2(cod)2O2 is in the catalytic synthesis of complex organic molecules. It can efficiently promote a range of carbon-carbon bond forming reactions such as cross-coupling reactions. For instance, Ir2(cod)2O2 is commonly utilized in the Sonogashira coupling, which involves the formation of carbon-carbon bonds between terminal alkynes and aryl or vinyl halides. This catalyst enables the synthesis of diverse molecules with high selectivity and functional group tolerance.Ir2(cod)2O2 is also employed in the hydrogenation of unsaturated compounds. It can selectively hydrogenate functional groups such as alkenes, alkynes, and ketones to the corresponding saturated counterparts. This catalyst is particularly useful in the reduction of conjugated systems, allowing for regio- and stereo-selective transformations. The hydrogenation reactions catalyzed by Ir2(cod)2O2 find applications in the synthesis of fine chemicals, pharmaceuticals, and agrochemicals.Furthermore, Ir2(cod)2O2 is utilized in various oxidation reactions. It can catalyze the oxidation of alcohols to aldehydes, ketones, or carboxylic acids with high activity and selectivity. Additionally, it can facilitate the oxidative coupling of arylboronic acids, enabling the synthesis of biaryl compounds. The ability of Ir2(cod)2O2 to directly activate hydrogen peroxide as an oxidant makes it an attractive catalyst for environmentally friendly oxidation processes.Moreover, Ir2(cod)2O2 plays a crucial role in the synthesis of functional materials. It can catalyze the polymerization of olefins, leading to the formation of polymers with controlled molecular weights and narrow polydispersity. The resulting polymers exhibit unique properties and find applications in areas such as coatings, adhesives, and biocompatible materials.Ir2(cod)2O2 is also employed as a catalyst in the preparation of cyclic organic compounds. It can promote cyclization reactions, allowing for the synthesis of cyclic structures with high efficiency and regioselectivity. This application is significant in the production of natural products, pharmaceuticals, and other bioactive molecules.In summary, di-mu-methoxobis(1,5-cyclooctadiene)diiridium(I) (Ir2(cod)2O2) is a versatile catalyst used in diverse organic transformations. Its applications include carbon-carbon bond formation, hydrogenation, oxidation, polymerization, and cyclization reactions. As a result, Ir2(cod)2O2 plays a crucial role in the synthesis of complex organic molecules, functional materials, and cyclic compounds. Its high activity, selectivity, and functional group tolerance make it a valuable tool in synthetic chemistry.