Bis(cyclopentadienyl)ruthenium CAS:1287-13-4 99%
| Catalog Number | XD90652 |
| Product Name | Bis(cyclopentadienyl)ruthenium |
| CAS | 1287-13-4 |
| Molecular Formula | C10H10Ru |
| Molecular Weight | 231.256 |
| Storage Details | Ambient |
| Harmonized Tariff Code | 29310099 |
Product Specification
| Appearance | White to light brown crystals or crystalline powder |
| Assay | 99% |
The functionalization of methyl D-glucopyranosides at positions 4 and 6 with bulky moieties was carried out by using ferrocenyl and ruthenocenyl substituents. The synthesis succeeded by reaction of the methyl D-glucopyranosides with the corresponding metallocene monocarbaldehyde dimethyl acetal catalysed by iodine in acetonitrile. The resulting compounds methyl 4,6-O-(metallocenylmethylidene)-α-D-glucopyranoside (M=Fe (1) and M=Ru (3)) and methyl 4,6-O-(metallocenylmethylidene)-β-D-glucopyranoside (M=Fe (2) and M=Ru (4)) were characterized by (1)H and (13)C NMR spectroscopy, by crystal structure determination as well as elemental analysis.
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